Re: Zagreb to Ljubljana, Slovenia: Buy train ticket in advance necessary?
I've bought tickets for Zagreb - Ljubljana in Zagreb minutes before the train left. It's usually not a problem. Trains aren't like planes. If you want peace of mind (you never know if there's going to be a queue at the ticket office) just buy your ticket when you arrive in Zagreb. The 9 and 13 o'clock trains don't have compulsory reservation, so a ticket for the right date will be valid on both.
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