RE: Santiago, Valparaiso or Vina del Mar?
I would recommend to stay in Santiago and to make a tour to see the highlights of Santiago (Cerro Santa Lucia, Mercato Central, Plaza de Armas with cathedral, post office, Palacio de la Moneda and Cerro San Cristobal).
You have to take a bus to Valparaiso, about a 1 1/2 hours drive; they are leaving from the metro station Pajaritos. There are 2 companies with regular busses to V. and they are leaving at least every 30 minutes.
The last day you can visit Valparaiso. Specially the hills around the harbour and the cable cars are worth a visit.
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