Can anyone tell me if this service is available on a Sunday ? I am planning on taking train from Rome To Naples and then Pompei on a Sunday in April 2013. Are there any restrictions on a Sunday ?
Yes it is.
Plenty of direct trains from naples to Pompei. About 45 minutes travelling.
Check this: http://www.vesuviana.it/
You are right to be concerned as some local traffic does reduce a lot on Sundays and holidays, but if you look at the Naples to Sorrento schedule at the website above (or jump straight to vesuviana.it/web/files/Orari... ), you'll notice (if you can read Italian) that only two of the trains don't run on Sunday, the one at 6:44 a.m. and the one at 7:39 a.m. Since you probably won't get to Naples by then, no problem ;-)
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and the name of the right station to get out for the excarvations in Pompeji will be :