RE: Transportation to Sukhothai
According to my Lonely Planet guide, there are buses from Phitsanulok to Sukhothai every half-hour or so (it doesn't have the time for the 1st one, sorry, but given their frequency the first one should be reasonably early); the journey takes an hour. The bus station in Phitsanulok is 2km out from the centre (the train station is in the middle of town) - the LP guide reckons that city bus No. 1 will take you there.
Hope this helps...
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