If you're looking for somewhere very quite and secluded then there's a Posada near to Parati (The-Pousada-Picinguaba-Hotel) that is very nice. It's a drive into Parati itself though so only book if you 'really' want to be away from it all. There are some nice Posada's in Parati itself but it will be busier.
Definately visit the beaches of Trindade on your visit to Parati... very beautiful. Other things to do are a schooner trip (although if you book at the Posada they have their own boat to take you on trips round the islands). A jeep ride into the rain forest to visit the waterfalls is also fun.
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