The best is to get a transfer, a shared minivan, to the address you want. There are two companies operating from the airport to the city. You don't really need to book it in advance. http://www.carrielsur.cl/ http://www.carrielsur.cl/transfer.html The prices are set according to where you are going in the city and they take you to any address. If you don't speak Spanish, have the address you want on a piece of paper to show. They are by the main door outside arrivals. They operate 24 hrs a day, every day of the year.
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