If you mean Ciano near Oviedo, it's a long way from Madrid.
You can take the Airport Express bus (2 euro, pay the driver) to Atocha station in Madrid, then the train to Oviedo (around 5 hours):
or there is an ALSA bus from T4 to Oviedo:
From Oviedo you could take the Cercanias line C2 to Ciano:
I have not been to Ciano or Oviedo: I have only researched possibilities for you. Other VT-ers may know a simpler way of getting from Madrid Barajas to Ciano.
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